# Preservation of phase space volume and Liouville's theorem

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- 5104

Consider a phase space volume element \(dx_0\) at *t*=0, containing a small collection of initial conditions on a set of trajectories. The trajectories evolve in time according to Hamilton's equations of motion, and at a time *t* later will be located in a new volume element \(dx_t\) as shown in the figure below:

**Figure 1:**

How is \(dx_0\) related to \(dx_t\)dxdd ? To answer this, consider a trajectory starting from a phase space vector \(x_0\) in \(dx_0\) and having a phase space vector \(x_t\) at time *t* in \(dx_t\). Since the solution of Hamilton's equations depends on the choice of initial conditions, \(x_t\) depends on \(x_0\) :

\[ x_0 = \left ( p_1 (0), \cdots , p_N(0), r_1(0), \cdots , r_N (0) \right ) \]

\[ x_0 = \left ( p_1 (t), \cdots , p_N(t), r_1(t), \cdots , r_N (t) \right ) \]

\[ x^i_t = x^i_t \left ( x^1_0 , \cdots , x^{6N}_0 \right ) \]

Thus, the phase space vector components can be viewed as a coordinate transformation on the phase space from *t*=0 to time *t*. The phase space volume element then transforms according to

\[ dx_t = J (x_t ; x_0 ) dx_0 \]

where \(J (x_t ; x_0 )\) is the Jacobian of the transformation:

\[ J (x_t ; x_0 ) = \frac {\partial (x^1_t \cdots x^n_t )}{\partial (x^1_0 \cdots x^n_0 )} \]

where *n*=6*N*. The precise form of the Jacobian can be determined as will be demonstrated below.

The Jacobian is the determinant of a matrix M,

\[ J (x_t ; x_0 ) = \text {det} (M) = e^{TrlnM} \]

whose matrix elements are

\[ M_{ij} = \frac {\partial x^i_t}{\partial x^j_0}\]

Taking the time derivative of the Jacobian, we therefore have

\[ \frac {dJ}{dt} = Tr \left ( M^{-1} \frac {dM}{dt} \right ) e^{TrlnM} \]

\[ = J \sum _{i=1}^n \sum _{j=1}^n M^{-1}_{ij} \frac {dM_{ij}}{dt} \]

The matrices M \(_{-1} \) and \( \frac {dM}{dt} \) can be seen to be given by

\[ M^{-1}_{ij} = \frac {\partial x^i_0}{\partial x^j_t} \]

\[\frac {dM_{ji}}{dt} = \frac {\partial \dot {x}^i_t}{\partial x^i_0} \]}}

Substituting into the expression for *dJ*/*dt* gives

\[\frac {dJ}{dt} = J \sum _{i,j=1}^n \frac {\partial x^i_0}{\partial x^j_t} \frac {\partial \dot {x}^i_t}{\partial x^i_0} \]

\[= J \sum _{i,j,k=1}^n \frac {\partial x^i_0}{\partial x^j_t} \frac {\partial \dot {x}^i_t}{\partial x^k_t} \frac {\partial x^k_t}{\partial x^i_0} \]

where the chain rule has been introduced for the derivative \(\frac {\partial x^j_t}{\partial x^i_0}\). The sum over *i* can now be performed:

\[\sum _{i=1}^n \frac {\partial x^i_0}{\partial x^j_t} \frac {\partial x^k_t}{\partial x^i_0} = \sum ^n_{i=1} M^{-1}_{ij} M_{ki} = \sum ^n_{i=1} M_{ki}M^{-1}_{ij} = \delta _{kj} \]

Thus,

\[\frac {dJ}{dt} = J \sum ^n_{j,k=1} \delta _{jk} \frac {\partial \dot {x}^j_t}{\partial x^k_0}\]

\[ J \sum ^n_{j=1} \frac {\partial \dot {x}^j_t}{\partial x^j_t} = J \nabla _x \cdot \dot {x}\]

or

\[ \frac {dJ}{dt} = J \nabla _x \cdot \dot {x} \]

The initial condition on this differential equation is \(J (0) \equiv J (x_0; x_0) = 1 \). Moreover, for a Hamiltonian system \(\nabla _x \cdot \dot {x} = 0 \). This says that *dJ*/*dt*=0 and *J*(0)=1. Thus, \(J (x_t ; x_0 ) = 1 \). If this is true, then the phase space volume element transforms according to

\[ dx_o = dx_t\]

which is another conservation law. This conservation law states that the phase space volume occupied by a collection of systems evolving according to Hamilton's equations of motion will be preserved in time. This is one statement of Liouville's theorem.

Combining this with the fact that *df*/*dt*=0, we have a conservation law for the phase space probability:

\[ f(x_o, o) dx_o = f(x_t,t)dx_t\]

which is an equivalent statement of Liouville's theorem.