# The Bohr Atom

As we know it the atom is made up of neutrons, protons, and electrons. While the neutrons (0 charge), and the protons (positive charge) make up the nucleus of the atom, the electron (negative charge) circle around the nucleus much like the orbiting of planets around the sun. According to old theories it was known that electrons are in constant motion around the nucleus while emitting energy. According to this idea as the electrons lost energy they would get closer and closer to the nucleus and eventually crash into it. This problem was solved when Niels Bohr created a model of a hydrogen atom.

## The Bohr Atom 1. Electrons move around the nucleus of an atom in circular motion.
2. Electrons have a set number of orbitals, ring-like paths around the nucleus, they can travel in called stationary states. If the electron stays in one orbital, the energy of the electron remains constant. The first orbital is n=1, the second orbital n=2 and so on. (These values of n are called quantum numbers.) Figure 1: In this standing wave on a circular string, the circle is broken into exactly 8 wavelengths. A standing wave like this can have 0,1,2, or any integer number of wavelengths around the circle, but it cannot have a non-integer number of wavelengths like 8.3. In quantum mechanics, angular momentum is quantized for a similar reason. Figure used with permission from Wikipedia.

3. Electrons can only move from one orbital to another allowed orbital at one time. If an electron drops down from n=2 to n=1 energy is emitted, and if the electron moves up from n=1 to n=2 energy is absorbed. The amount of energy that is either absorbed or emitted is called quanta. In his model of the atom Bohr used Planck's quantum hypothesis, and of course his knowledge from prior findings. Bohr uses Ryberg's formula for explaining how the electrons emit light as they move from one orbital to another. The point Bohr was trying to get across is that energy is not continuous in an atom. We can say that an atom that is in the lowest energy level is in the ground state, and when it moves to a higher level it is in an excited state. The energy of a photon, lost or gained, is calculated using Planck's equation: (h is Planck's constant, 6.62607 x 10-34 J s / cycles, and v stands for frequency in cycles/s)

$\text{Energy Difference} (\Delta E) = h\nu$

Bohr's model allows us to calculate the radii of the orbits that are allowed for an electron to travel. It also allows us to calculate electron velocities and energy in these orbits. With the equation below we can calculate allowed energy levels for a Hydrogen atom. (-RH is a constant value of 2.179 x 10-18 Joules)

$E_n=-R_H \dfrac{1}{n^2}$

When an electron drops from a higher level for example from n=2 to a lower energy level, n=1, it emits a specific wavelength distinct to that element. To calculate the difference between the two energy levels, the equation below is used. Subscript i stands for initial, (initial energy= Ei and initial quantum number= ni) while subscript f stands for final (final energy= Ef and final quantum number= nf).

$\text{Energy Difference (} \Delta E \text {)} = E_f-E_i = -R_H \left ( \dfrac{1}{n_f^2} - \dfrac{1}{n_i^2}\right ) = R_H \left ( \dfrac{1}{n_i^2} - \dfrac{1}{n_f^2}\right )$

The Bohr model also helps us understand how cations are made. This is through the concept of Ionization Energy, the energy to remove an electron from its ground state. After the electron is free the atom is ionized. Ei stands for the ionization energy of the hydrogen atom. The equation below however works for any species that have one electron like hydrogen (for example, He+ and Li2+) where Z is the atomic number of the hydrogen-like atom:

$E_n=-Z^2R_H \dfrac{1}{n^2}$

If we want to find the energy associated with a change in quantum number of a hydrogen-like atom, we can combine this equation with the previous one to form

$\Delta E=-Z^2R_H \left ( \dfrac{1}{n_f^2} - \dfrac{1}{n_i^2} \right )$

If the result of this equation is negative, meaning that the electron is moving down in energy levels (quantum number n), the result is that radiation is emitted. If the result is positive, and the electron is moving up in energy levels (quantum number n), radiation was absorbed.

Although Bohr’s discovery was a huge accomplishment, this model of the atom is not without its flaws. Because it is only designed for the hydrogen atom and hydrogen-like ions, it cannot explain the electron emission of atoms or ions that contain more than one electron.

## History of the Bohr Atom

As stated before, we all now know that the atom is made up of neutrons, protons, and electrons. However, how this knowledge was found and how the Bohr Atom was created cannot be understood without knowledge of the history of the discoveries that occurred before the creation of the Bohr Atom. Although not all of these discoveries are necessary to know, there are a few significant discoveries that are important to know.

### Dalton's Atomic Theory

In 1808, John Dalton published a book named A New System of Chemical Philosophy. In the book, he shared his conclusions on the atom, which became known as Dalton's Atomic Theory. The assumptions of the theory were:

1. All matter, or more specifically elements, are made up of tiny, indivisible particles called atoms. And, these atoms, during a chemical reaction, cannot be destroyed nor created.
2. The atoms of a specific element are identical (including their mass).
3. Elements can be identified based on their individual masses. This is because the masses and properties of the atoms of a specific element are different from the masses and properties of the atoms of a different element.
4. When the atoms of elements react, they must combine in simple whole number ratios.

### Discovery of the Electron and the Plum Pudding Model

In 1897, J.J. Thompson helped establish electrons as being a negatively charged component of atoms using cathode rays. However, how exactly the electrons fit into the atom was unknown at that time. As seen in the figure right above, Thompson theorized in 1904, that the atom was a positively charged "nebulous cloud" which contained evenly dispersed negatively charged electrons. This became known as the Plum Pudding Model due to its similarity to the popular dessert (with fruit being dispersed throughout gelatin).

### The Photoelectric Effect

In 1887, the Photoelectric Effect was observed by Heinrich Hertz, and then later improved upon by Albert Einstein in 1905. The theory stated that under certain conditions, light, when shined upon a metal, would cause the metal to emit a stream of particles. The particles were found to be electrons, and the number of electrons emitted was found to be based on the frequency of the light. Einstein suggested that each particle of light could be classificed as a photon. ### The Rutherford Model By 1911, Ernest Rutherford and his two assistants Hans Geiger and Ernest Marsden had concluded that the Plum Pudding Model was incorrect based on their Gold Foil Experiment. The results of the experiment led to three conclusions about the atom:

1. The atom has a very compact nucleus, which is a region in the center of the atom which holds a majority of the mass and positive charge of the atom.
2. The positive charge of each atom is different from the charge of a different atom. And that the number of electrons inside the atom is equal to the number of protons inside the atom (leading to a neutrally charged atom).
3. Negatively charged particles (electrons) orbit the nucleus at any distances (much like planets orbiting the sun).

However, based on electrodynamics, the Rutherford Model was found to be unstable. Seeing the problems with the Rutherford Model, Bohr decided to formulate an atom that would correct the instability problems of the Rutherford Model.

## References

1. Petrucci, Ralph H., William S. Harwood, Geoffery F. Herring, and Jeffry D. Madura. General Chemistry. 9th ed. New Jersey: Pearsin Prentice Hall, 2007.