# 6.2: Classical Description of the Vibration of a Diatomic Molecule

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A classical description of the vibration of a diatomic molecule is needed because the quantum mechanical description begins with replacing the classical energy with the Hamiltonian operator in the Schrödinger equation. It also is interesting to compare and contrast the classical description with the quantum mechanical picture.

The motion of two particles in space can be separated into translational, vibrational, and rotational motions. The internal motions of vibration and rotation for a two-particle system can be described by a single reduced particle with a reduced mass \(μ\) located at \(r\).

For a diatomic molecule, Figure \(\PageIndex{1}\), the vector r corresponds to the internuclear axis. The magnitude or length of r is the bond length, and the orientation of r in space gives the orientation of the internuclear axis in space. Changes in the orientation correspond to rotation of the molecule, and changes in the length correspond to vibration. The change in the bond length from the equilibrium bond length is the normal vibrational coordinate Q for a diatomic molecule.

We can use Newton's equation of motion

\[\vec{F}= m \vec{a} \label {6-8}\]

to obtain a classical description of how a diatomic molecule vibrates. In this equation, the mass, m, is the reduced mass μ of the molecule, the acceleration, \(a\), is \(d^2Q/dt^2\), and the force, \(f\), is the force that pulls the molecule back to its equilibrium bond length. If we consider the bond to behave like a spring, then this restoring force is proportional to the displacement from the equilibrium length, which is Hooke's Law

\[ F = - kQ \label {6-9}\]

where \(k\) is the **force constant**. Hooke's Law says that the force is proportional to, but in opposite direction to, the displacement, \(Q\). The force constant, \(k\), reflects the stiffness of the spring. The idea incorporated into the application of Hooke's Law to a diatomic molecule is that when the atoms move away from their equilibrium positions, a restoring force is produced that increases proportionally with the displacement from equilibrium. The potential energy for such a system increases quadratically with the displacement. (See Exercise 6.9 below.)

\[ V (Q) = \dfrac {1}{2} k Q^2 \label {6-10}\]

Hooke's Law or the harmonic (i.e. quadratic) potential given by Equation \(\ref{6-10}\) is a common approximation for the vibrational oscillations of molecules. The magnitude of the force constant \(k\) depends upon the nature of the chemical bond in molecular systems just as it depends on the nature of the spring in mechanical systems. The larger the force constant, the stiffer the spring or the stiffer the bond. Since it is the electron distribution between the two positively charged nuclei that holds them together, a double bond with more electrons has a larger force constant than a single bond, and the nuclei are held together more tightly. In fact IR and other vibrational spectra provide information about the molecular composition of substances and about the bonding structure of molecules because of this relationship between the electron density in the bond and the bond force constant. Note that a stiff bond with a large force constant is not necessarily a strong bond with a large dissociation energy.

In view of the above discussion, Equation \ref{6-8} can be rewritten as

\[\dfrac {d^2 Q(t)}{dt^2} + \dfrac {k}{\mu} Q(t) = 0 \label {6-11}\]

Equation \(\ref{6-11}\) is the equation of motion for a classical harmonic oscillator. It is a linear second-order differential equation that can be solved by the standard method of factoring and integrating as described in Chapter 5.

The energy of the vibration is the sum of the kinetic energy and the potential energy. The momentum associated with the vibration is

\[P_Q = \mu \dfrac {dQ}{dt} \label {6-12}\]

so the energy can be written as

\[ E = T + V = \dfrac {P^2_Q}{2 \mu} + \dfrac {k}{2} Q^2 \label {6-13}\]

We can generalize this discussion to any normal mode in a polyatomic molecule. The normal coordinate associated with a normal mode can be thought of as a vector \(Q\), with each component giving the displacement amplitude of a particular atom in a particular direction. Equation \ref{6-11} then applies to the length of this vector \(Q = |Q|\). As \(Q\) increases, it means the displacements of all the atoms that move in that normal mode increase, and the restoring force increases as well.

## Contributors

David M. Hanson, Erica Harvey, Robert Sweeney, Theresa Julia Zielinski ("Quantum States of Atoms and Molecules")