16.12: Additional Exercises
- Page ID
- 166435
General Review
16-1 Identify which of the following dienes are isolated, conjugated, or cumulated.
16-2 Identify which pathway gives the thermodynamic or the kinetic product and provide a reason for your answer.
16-3 Draw the resonance structures of the following molecule.
16-4 Provide the final product of the following reaction.
16-5 Predict the final product for the following reactions.
16-6 For the following compound, predict which bonds could be broken to give the most probable Diels-Alder dienes that reacted to make the compound. Provide the resulting dienes from the prediction.
16-7 Give the final product of the following reaction chain..
1,2- and 1,4-Addition to Conjugated Dienes
16-8 Predict all possible products of the following reaction.
16-9 Identify the kinetic and thermodynamic products of the previous problem, 16-8.
16-10 Predict the kinetic product(s) of the following reaction and provide proper IUPAC nomenclature.
Allylic Radicals
16-11 Draw arrows to show the movement of electrons in the following allylic radical.
16-12 Show the products of the following reactions.
16-13 Choose the correct answer of the following reaction.
SN2 Displacement Reactions of Allylic Halides and Tosylates
16-14 Predict the products of the following reactions.
16-15 Choose the correct IUPAC nomenclature of the product of the following reaction and provide its structure.
a) (3R)-3-ethoxycyclohex-1-ene
b) (3S)-3-ethoxycyclohex-1-ene
c) ethoxycyclohexane
d) cyclohexa-1,3-diene
16-16 Predict the product of the following reaction.
Diels-Alder Reactions
16-17 Predict the products of the following Diels-Alder reactions.
16-18 Predict the product of the following reaction.
16-19 Choose the correct answer.