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22.13: Additional Exercises

  • Page ID
    166444
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    General Review

    22-1 Suggest a carboxylic acid and an acid derivative that could be reacted together to form the following molecule.

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    22-2 For the following reaction, predict the product if:

    • only one equivalent of the Grignard reagent was used (and the product could be isolated)
    • if two equivalents were used (followed by an acid workup)

    5VJv7CoHYm7_RMCXLOJ0_LyFJk1r7S_voV1KZRwfLkBvZb2Ap_CPE0DjC3Lz82rx1Ks85FdK9k38bQgmaR9CiwQE9kuN4bxdfnrYPAmLLqJMWec5jXEmgYMIrXjq3tu9eAl0e_OB

    22-3 Provide the final products of the following reactions.

    FOUUX6o-r4WUGHpxudFZEbYYdioaS14BcPNsXdHxgfz6VmI1JW1xLvYQ4MdcVk7M5ALfecvGCkvt1oMWe0p6JgGSzGAsSCeZT8LPUvFWvpvUG2gXFz_UCE9O5_fWb3bQ6WIXMmS3

    22-4 Predict the final product of the following reaction.

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    Interconversion of Acid Derivatives by Nucleophilic Acyl Substitution

    22-5 Predict the interconverted acid derivatives of the following reactions.

    3MQjONyAs2vFNgmzhw77V_DHpF5Q4N8EYUMIqDIwBC0wjN0xKJ_huJDkFKOTE9og0msF19bU9T6ci-9xyVBZ2QZFOLJzq08TD-iicvSTB_mSkG75VZneFf81yj8j-34voYvKhbG7

    22-6 Predict the structure of the product and give its IUPAC nomenclature.

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    22-7 Choose the correct answer for the product of the following reaction.

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    GEebuQUoB2PAtM86pM2ssaTleBDdN2ySU6jVfCYlf2fUITuQWz-4BORza9tDjy1R4KRMUBk9WHdYJZNzYVuQ6vvjxfTJvoCdW0dm0NKCk2iw7S5rFPebgls1bwC8k3qh3xQH1zSq

    Transesterification

    22-8 Choose the correct IUPAC nomenclature of the product of the following reaction.

    w5YNygw7k73IE7U1oY6i4Hh_sFNX-vnYUv6QJMmLCjDxMrR2-BlhhjYC218DZcEYY1fpApCWvq6pcEgMtGiZYQTlNt6dnVBcZx-wOYpX8K3LqFDvyASnxlH-WMZ8-LRXC2ny5IYa

    a) ethyl butanoate

    b) propan-2-yl butanoate

    c) dipropyl carbonate

    d) propyl butanoate

    22-9 Explain why transesterification can be done under acidic or basic conditions.

    22-10 Give the products of the following transesterification reactions.

    XqEsiYa6DldXFFssV-PHyApj8OXRQI4FidHKT3l0sVzgL-FdTtuOhvNWlBETND0Hn0AoSot750YKrVJfwM0MokXnbxuCNZ28q3n8BRKLFtyxhYNMFYo1Ot2LopQrnjKca4u-_z7g

    Hydrolysis of Carboxylic Acid Derivatives

    22-11 Provide the correct structure of the product of the following hydrolysis reaction.

    5AFYQfb0gO972OnrOyTJqMmfG-VRQxn1TQwcGayJSwV8cn29CEEDl7WJfIRgU0DNmudBxOaYr7CpT6q4d_XJ91cZ84LAPZX0mqBb74n3yPnVl9ymMnsYViI8MXrj5mCCKZz-F07B

    22-12 Provide the structure of all the products resulting from the hydrolysis of the following triglyceride.

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    22-13 Provide the structures and IUPAC nomenclature of the products.

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    Reduction of Acid Derivatives

    22-14 Give the structure of the product of the following reaction.

    VYS9UKy0twKA6UojRuYXdO7fgYYNwxlEQoII1pyuqjoDameyU-7j_u0O7biN6BBnzh7AI1UvAYcNlqtEhwSPF4qO733BED1C3wYifIyRAJPiCKFFDJ9WenKi8FU2El83QYLMjHtA

    22-15 Provide the structure of all the products (including leaving groups) formed in the following reaction.

    2al-AhNdLc55FrNt37pEVQMotRJwZPYwnrl11zVWmS3uHtlZqkewMRGiwQaYq1ZWApYIqYMHMbI8Gk2-leRyGbXOMZCGqjFKqwzosblsmlsAppO9xGT5-9wmoHXs-4luX_E4YWno

    22-16 Choose the correct answer that gives the products of a fully reduced 1,3-dimethyl-1,3-diazinan-2-one.

    -tcgdKefLUhGyaC78_NVA1EPD_SBGO0GbWOgtUu18mfUgxsYAVWHxG4hETFyozF6bswSa3XlZV-fyeD5Hi5y6Hj00n7w_cnLcTjVJEgqOF3C3342WKALfy9VDQZFMo6osTyrTj5o

    Ibx0vctffCCmTMVjTlrSpTTnyH5_6x0N8w5pejSu_pIDyP6xvTx8pz3Hs5Tk5IlOSHciVJ1K0H0sKDK14rCRZNAEMECF5j_KZuKwztcICE6BdXHRzFC6J_GVwV7msNGwYlqM9Orc

    Reactions of Acid Derivatives with Organometallic Reagents

    22-17 Predict the product of the following reaction.

    Ov2KmcWgp6rCvbHndqFNvP1NsHHgPCTQxD9d5Wc5vagF1mvoG3qH1usIAb6jy6fU6tRCdsIO_NfbFallwfAcP8kTcauhEj72OCohfJ80FSw6ky4z4TK6ItsyrkJ18vzZUxjPQRPR

    22-18 Choose the correct IUPAC nomenclature of the product of the following reaction.

    82qvhrSbWrrATcPsZSf08PQPHuUrmapET4osnHDPj-jSHsntqZIvN9xP2AxQIxEj-3Y4KDi_0VTKtLPMiRaDYne__SETCGe5dcNdiaVVCUa1yKX5SpqIPM45DDRSPpypazbtnFoW

    a) 6-amino-5-chlorohexan-2-one

    b) 6-amino-5-chloro-2-methylhexan-2-ol

    c) 6-amino-4-chloro-2-methylhexan-2-ol

    d) 4-chloro-2-methylpiperidin-2-ol

    22-19 Decide whether or not the following reaction is the best way to obtain the final product. If not, suggest a better route of synthesis.

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    22.13: Additional Exercises is shared under a CC BY-NC-SA 4.0 license and was authored, remixed, and/or curated by LibreTexts.

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