4: Carbon-Heteroatom Bond-Forming Reactions
- Page ID
- 168793
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Asymmetric carbon-heteroatom bond formation is among the fundamentally important reactions. This module covers the carbon-heteroatom bond-forming reactions using transition-metal-complex as well as the chiral Lewis acid catalyzed protocols.
- 4.2: Aza-Claisen Rearrangement and Related Reactions
- Aza-Claisen rearrangement, known as the Overman rearrangement, has been extensively studied that allows us to synthesize chiral allylic amines from achiral allylic imidates with excellent enantioselectivity.
- 4.8: Boration of Alkenes
- Organoboranes are useful reagents for organic synthesis. Recently, catalytic methods have been developed for enantioselective boration of unsaturated substrates.