# 16.6: Batteries: Using Chemistry to Generate Electricity

Skills to Develop

• Identify the substance being oxidized and the substance being reduced in an oxidation-reduction reaction.
• Identify the anode and the cathode given a diagram of an electrolysis apparatus that includes the compound being electrolyzed.
• Describe how batteries can produce electrical energy.

Electricity is an important form of energy that you use every day. It runs your calculators, cell phones, dishwashers, and watches. This form of energy involves moving electrons through a wire and using the energy of these electrons. Electrochemical cells used for power generation are called batteries. Although batteries come in many different shapes and sizes there are a few basic types. You won't be required to remember details of the batteries, but some general information and features of each type is presented here. Batteries are one way of producing this type of energy. Many important chemical reactions involve the exchange of one or more electrons, and, therefore we can use this movement of electrons as electricity. These reactions are called oxidation-reduction (or "redox") reactions.

### Oxidation and Reduction

Reactions in which electrons are transferred are called oxidation-reduction (or "redox") reactions. There are two parts to these changes: one atom must lose electrons and another atom must gain them. These two parts are described by the terms "oxidation" and "reduction".

Originally, a substance was said to be oxidized when it reacted with oxygen. Today, the word "oxidized" is still used for those situations, but now we have a much broader second meaning for these words. Today, the broader sense of the word oxidation is defined as losing electrons. When a substance loses electrons, its charge will increase. This may feel a bit backwards, but remember that electrons are negative. If an atom loses electrons, it is losing negative particles so its charge will increase.

The other half of this process, the gaining of electrons, also needs a name. When an atom or an ion gains electrons, the charge on the particle goes down. For example, if a sulfur atom whose charge is zero $$\left( 0 \right)$$ gains two electrons, its charge becomes $$\left( -2 \right)$$ and if an $$\ce{Fe^{3+}}$$ ion gains an electron, its charge changes from $$+3$$ to $$+2$$. In both cases the charge on the particle is reduced by the gain of electrons. Remember that electrons have a negative charge, so gaining electrons will result in the charge decreasing. The word reduction is defined to mean gaining electrons and the reduction of charge.

In chemical systems, these two processes (oxidation and reduction) must occur simultaneously and the number of electrons lost in the oxidation must be the same as the number of electrons gained in the reduction. In oxidation-reduction reactions, electrons are transferred from one substance to another. Here's an example of an oxidation-reduction reaction.

$2 \ce{Ag^+} \left( aq \right) + \ce{Cu} \left( s \right) \rightarrow 2 \ce{Ag} \left( s \right) + \ce{Cu^{2+}} \left( aq \right)$

In this reaction, the silver ions are gaining electrons to become silver atoms. Therefore, the silver ions are being reduced and the charge of silver is decreasing. The copper atoms are losing electrons to become copper $$+2$$ ions and are therefore, being oxidized and the charge of copper is increasing. Whenever a chemical reaction involves electrons being transferred from one substance to another, the reaction is an oxidation-reduction reaction (or a redox reaction).

Half-equations are very helpful in discussing and analyzing processes but half-reactions cannot occur as they appear. The half-reactions for the reaction above would be:

$2 \ce{Ag^+} \left( aq \right) + 2 \ce{e^-} \rightarrow 2 \ce{Ag} \left( s \right)$

$\ce{Cu} \left( s \right) \rightarrow \ce{Cu^{2+}} \left( aq \right) + 2 \ce{e^-}$

Both oxidation and reduction must occur at the same time so the electrons are donated and absorbed nearly simultaneously. The two half-reactions may be added together to represent a complete reaction. In order to add the half-reactions, the number of electrons donated and the number of electrons accepted must be equal.

Example 9.3.1

For each reaction, identify what is oxidized and what is reduced.

a) $$\ce{Zn} + \ce{HCl} \rightarrow \ce{H_2} + \ce{ZnCl_2}$$

b) $$\ce{Fe} + \ce{O_2} \rightarrow \ce{Fe_2O_3}$$

c) $$\ce{NaBr} + \ce{I_2} \rightarrow \ce{NaI} + \ce{Br_2}$$

Solution:

In order to determine what is being oxidized and reduced, we must look at charges of atoms and see if they increase or decrease. (Remember, elements have no charge. In a compound, we can use our periodic table and what we learned in Chapter 4 to assign charges.) If the charge increases, the atom was oxidized. If the charge decreases, the atom was reduced.

a) This reaction written with charges is:

$\ce{Zn^0} + \ce{H^+Cl^-} \rightarrow \ce{H_2^0} + \ce{Zn^{2+}Cl_2^-}$

$$\ce{Zn}$$ is oxidized because it went from $$0$$ to $$+2$$. $$\ce{H}$$ is reduced because it went from $$+1$$ to $$0$$. $$\ce{Cl}$$ was neither oxidized nor reduced.

b) This reaction written with charges is:

$\ce{Fe^0} + \ce{O_2^0} \rightarrow \ce{Fe_2^{3+}O_3^{2-}}$

$$\ce{Fe}$$ is oxidized because it went from $$0$$ to $$+3$$. $$\ce{O}$$ is reduced because it went from $$0$$ to $$-2$$.

c) This reaction written with charges is:

$\ce{Na^+Br^-} + \ce{I_2^0} \rightarrow \ce{Na^+I^-} + \ce{Br_2^0}$

$$\ce{Br}$$ is oxidized because it went from $$-2$$ to $$0$$. $$\ce{I}$$ is reduced because it went from $$0$$ to $$-1$$. $$\ce{Na}$$ was neither oxidized nor reduced as it stayed $$+1$$ the whole time.

### Batteries

Batteries are devices that use chemical reactions to produce electrical energy. These reactions occur because the produces contain less potential energy in their bonds than the reactants. The energy produced from excess potential energy not only allows the reaction to occur but also often gives off energy to the surroundings. Some of these reactions can be physically arranged so the energy given off is given off in the form of an electric current. These are the type of reactions that occur inside batteries. When a reaction is arranged to produce an electric current as it runs, the arrangement is called an electrochemical cell or a Galvanic Cell.

If a strip of copper is placed in a solution of silver nitrate, the following reaction takes place:

$2 \ce{Ag^+} \left( aq \right) + \ce{Cu} \left( s \right) \rightarrow 2 \ce{Ag} \left( s\right) + \ce{Cu^{2+}} \left( aq \right)$

In this reaction, copper atoms are donating electrons to silver ions so the silver ions are reduced to silver atoms and copper atoms are oxidized to copper (II) ions.

As the reaction occurs, an observer would see the solution slowly turn blue ($$\ce{Cu^{2+}}$$ ions are blue in solution) and a mass of solid silver atoms would build up on the copper strip.

The reaction we just described is not set up in such a way as to produce electricity. It is true that electrons are being transferred, but to produce electricity we need electrons flowing through a wire so we can use the energy of these electrons. This reactions, $$2 \ce{Ag^+} \left( aq \right) + \ce{Cu} \left( s \right) \rightarrow 2 \ce{Ag} \left( s \right) + \ce{Cu^{2+}} \left( aq \right)$$, is one that could be arranged to produce electricity. To do this, the two half-reactions (oxidation and reduction) must occur in separate compartments and the separate compartments must remain in contact through an ionic solution and an external wire.

In this electrochemical cell, the copper metal must be separated from the silver ions to avoid a direct reaction. Each electrode in its solution could be represented by a half-reaction.

$\ce{Cu} \rightarrow \ce{Cu^{2+}} + 2 \ce{e^-}$

$2 \ce{Ag^+} + 2 \ce{e^-} \rightarrow 2 \ce{Ag}$

The wire connects the two halves of the reaction, allowing electrons to flow from one metal strip to the other. In this particular example, electrons will flow from the copper electrode (which is losing electrons) into the silver electrode (which is where the silver ions gain the electrons). The cell produce electricity through the wire and will continue to do so as long as there are sufficient reactants ($$\ce{Ag^+}$$ and $$\ce{Cu}$$) to continue the reaction.

Electrochemical cells will always have two electrodes, the pieces of metal where electrons are gained or lost. (In this example, the strip of $$\ce{Ag}$$ metal and $$\ce{Cu}$$ metal are the electrodes.) The electrode where reduction occurs and electrons are gained is called the cathode. The electrode where oxidation occurs and electrons are lost is called the anode. Electrons will always move from the anode to the cathode. The electrons that pass through the external circuit can do useful work such as lighting lights, running cell phones, and so forth.

If the light bulb is removed from the circuit with the electrochemical cell and replaced with a voltmeter, the voltmeter will measure the voltage (electrical potential energy per unit charge) of the combination of half-cells. The size of the voltage produced by a cell depends on the temperature, the metals used for electrodes, and the concentrations of the ions in the solutions. If you increase the concentration of the reactant ion (not the produce ion), the reaction rate will increase and so will the voltage.

It may seem complicated to construct an electrochemical cell because of all their complexities. Electrochemical cells are actually easy to make and sometimes even occur accidentally. If you take two coins of different denomination and push them part way through the peel of a whole lemon and then connect the two coins with a wire, a small electric current will flow.

#### 1. Primary batteries - (dry cell batteries)

• non-rechargeable
• electrolytes are present as a paste rather than as a liquid
• general purpose battery used for flashlights, transistor radios, toys, etc.
• The basic dry cell battery consists of: zinc case as the anode (oxidation); a graphite rod is the cathode (reduction) surrounded by a moist past of either MnO2, NH4Cl, and ZnCl2 or in alkaline dry cells a KOH electrolytic paste.
• General reactions for the battery - manganese(IV) oxide-zinc cell (different batteries have different reactions - you don't need to remember any of these reactions)
 cathode 2MnO2(s) + 2 NH4+(aq)+ 2e- → Mn2O3 (s) + H2O(l) + 2NH3 (aq) anode Zn(s) → Zn2+(aq) + 2e-
• Maximum voltage 1.5V. By connecting several cells in series 90V can be achieved.
• Advantages of alkaline batteries - consistent voltage, increased capacity, longer shelf-life, and reliable operation at temperatures as low as -40°C
• Disadvantage - higher cost

#### 2. Secondary Batteries (storage batteries)

• rechargeable
• an example - lead-acid battery used in cars. Anode is grid of lead-antimony or lead-calcium alloy packed with spongy lead; Cathode is lead(IV) oxide. Electrolyte is aqueous sulfuric acid. Consists of numerous small cells connected in parallel (anode to anode; cathode to cathode).
• General reaction:
 cathode PbO2(s) + 4H+(aq)+ SO42-(aq) + 2e- → PbSO4 (s) + 2H2O(l) + 2NH3 (aq) anode Pb(s) + SO42-(aq) → PbSO4 (s) + 2e-
• Secondary batteries are recharged by passing a current through the battery in the opposite direction. In a car battery this occurs when the engine is running.
• Other examples include the nickel-iron alkaline battery, nickel-zinc batter, nickel-cadmium alkaline battery, silver-zinc, silver-cadmium

#### 3. Fuel Cells

• fuel cells are electrochemical cells that convert energy of a redox combustion reaction directly into electrical energy. Requires a continuous supply of reactants and a constant removal of products.
• Cathode reactant usually air or pure oxygen; anode fuel is a gas such as hydrogen, methane, or propane. Carbon electrodes typically contain a catalyst. The electrolyte is typically KOH.
• General reaction:
 cathode O2(g) + 2H2O(l) + 4e- → 4OH-(aq) anode 2H2 (g) + 4OH-(aq) → 4H2O(l) + 4e- net 2H2 (g) + O2(g) → 2H2O(l)
• Advantages - no toxic waste products (water is the only product); very efficient energy conversion (70-80% efficient)
• Disadvantage - too expensive for large-scale use.

### Summary

• Reactions in which there is a transfer of electrons is said to be an oxidation-reduction reaction or a redox reaction.
• A substance that loses electrons is said to be oxidized, and the substance that gains electrons is said to be reduced.
• Redox reactions can be used in electrochemical cells to produce electricity.
• Electrochemical cells are composed of an anode and cathode in two separate solutions. These solutions are connected by a salt bridge and a conductive wire.
• An electric current consists of a flow of charged particles.
• The electrode where oxidation occurs is called the anode and the electrode where reduction occurs is called the cathode.

### Vocabulary

• Electrochemical cell: An arrangement of electrodes and ionic solutions in which a redox reaction is used to make electricity (a.k.a., a battery)
• Electrolysis: A chemical reaction brought about by an electric current.
• Electroplating: A process in which electrolysis is used as a means of coating an object with a layer of metal.

### Contributors

• CK-12 Foundation by Sharon Bewick, Richard Parsons, Therese Forsythe, Shonna Robinson, and Jean Dupon.