13.20: Phase Diagram for Water

You need a special snow to make the best snowballs. This snow needs to be a little wet so the particles will stick together. Dry snow can be tightly pressed and will form snowballs because the higher pressure causes the snowflakes to melt somewhat. However, when you release the pressure, the snow goes back to a more solid form and the flakes no longer stick together.

Phase Diagram for Water

Water is a unique substance in many ways. One of these special properties is the fact that solid water (ice) is less dense than liquid water just above the freezing point. The phase diagram for water is shown in the figure below. Figure 13.20.1: Phase diagram for water.

Notice one key difference between the general phase diagram and the phase diagram for water. In water's diagram, the slope of the line between the solid and liquid states is negative rather than positive. The reason is that water is an unusual substance in that its solid state is less dense than the liquid state. Ice floats in liquid water. Therefore, a pressure change has the opposite effect on those two phases. If ice is relatively near its melting point, it can be changed into liquid water by the application of pressure. The water molecules are actually closer together in the liquid phase than they are in the solid phase.

Refer again to water's phase diagram (figure above). Notice point $$E$$, labeled the critical point. What does that mean? At $$373.99^\text{o} \text{C}$$, particles of water in the gas phase are moving very, very rapidly. At any temperature higher than than, the gas phase cannot be made to liquefy, no matter how much pressure is applied to the gas. The critical pressure $$\left( P_\text{C} \right)$$ is the pressure that must be applied to the gas at the critical temperature in order to turn it into a liquid. For water, the critical pressure is very high, $$217.75 \: \text{atm}$$. The critical point is the intersection point of the critical temperature and the critical pressure.

Summary

• Solid water is less dense than liquid water just above the freezing point.
• The critical temperature $$\left( T_\text{C} \right)$$ of a substance is the highest temperature at which the substance can possibly exist as a liquid.
• The critical pressure $$\left( P_\text{C} \right)$$ is the pressure that must be applied to the gas at the critical temperature in order to tun it into a liquid.
• The critical point is the intersection point of the critical temperature and the critical pressure.

Contributors

• CK-12 Foundation by Sharon Bewick, Richard Parsons, Therese Forsythe, Shonna Robinson, and Jean Dupon.