Skip to main content
Chemistry LibreTexts

Symmetry operation

  • Page ID
    19307
  • \( \newcommand{\vecs}[1]{\overset { \scriptstyle \rightharpoonup} {\mathbf{#1}} } \) \( \newcommand{\vecd}[1]{\overset{-\!-\!\rightharpoonup}{\vphantom{a}\smash {#1}}} \)\(\newcommand{\id}{\mathrm{id}}\) \( \newcommand{\Span}{\mathrm{span}}\) \( \newcommand{\kernel}{\mathrm{null}\,}\) \( \newcommand{\range}{\mathrm{range}\,}\) \( \newcommand{\RealPart}{\mathrm{Re}}\) \( \newcommand{\ImaginaryPart}{\mathrm{Im}}\) \( \newcommand{\Argument}{\mathrm{Arg}}\) \( \newcommand{\norm}[1]{\| #1 \|}\) \( \newcommand{\inner}[2]{\langle #1, #2 \rangle}\) \( \newcommand{\Span}{\mathrm{span}}\) \(\newcommand{\id}{\mathrm{id}}\) \( \newcommand{\Span}{\mathrm{span}}\) \( \newcommand{\kernel}{\mathrm{null}\,}\) \( \newcommand{\range}{\mathrm{range}\,}\) \( \newcommand{\RealPart}{\mathrm{Re}}\) \( \newcommand{\ImaginaryPart}{\mathrm{Im}}\) \( \newcommand{\Argument}{\mathrm{Arg}}\) \( \newcommand{\norm}[1]{\| #1 \|}\) \( \newcommand{\inner}[2]{\langle #1, #2 \rangle}\) \( \newcommand{\Span}{\mathrm{span}}\)\(\newcommand{\AA}{\unicode[.8,0]{x212B}}\)

    A symmetry operation is an isometry, i.e. a transformation under which two objects, or two configurations or an object, are brought to coincide. A symmetry operation is a Euclidean mapping: to each point of the first configuration there corresponds a point of the second configuration, the distances between two points are kept by the transformation, as are the angles.

    The two configurations/objects can be either congruent or enantiomorphous. Correspondingly, the symmetry operations are classed into two kinds:

    • symmetry operations of first kind: they relate congruent objects and consist of translations, rotations and screw rotations;
    • symmetry operations of second kind: they relate enantiomorphous objects and consist of inversion, reflections, rotoinversions, and glide reflections. There exist a 1:1 correspondence between rotoinversion and rotoreflections: the latter are more used in Schoenflies notation, whereas rotoinversions are preferred in Hermann-Mauguin notation.

    A symmetry operation is performed about a symmetry element.


    Symmetry operation is shared under a CC BY-NC-SA 4.0 license and was authored, remixed, and/or curated by Online Dictionary of Crystallography.