15.7A: Nitrogen Halides

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Nitrogen Halides

Most compounds NX₃ are known, together with the mixed ones for F and X. Some, for example NI₃.nNH₃ are explosive.
N₂F₂ and N₂F₄ are known.
The halogen azides XN₃ are also known.
NF₃ is exceptional in that it has no basic properties. Salts of NF₄⁺ such as [NF₄]⁺[BF₄]^– can be prepared and are powerful oxidizing agents.