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11.3: Baeyer-Villiger Rearrangement

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    190075

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    The Baeyer-Villiger rearrangement is the conversion of a ketone to an ester via the insertion of an oxygen atom next to the carbonyl.

    ERBaeyerVilliger.png

    The reaction involves initial addition of a peroxide to the carbonyl carbon. The resulting adduct undergoes rearrangement to form the ester.

    ERBaeyerVilligerMech.png

    Exercise \(\PageIndex{1}\)

    Predict the products of the following Baeyer-Villiger reactions.

    ERBaeyerVilligerExample.png
    Answer

    ERBaeyerVilligerSolution.png

    This page titled 11.3: Baeyer-Villiger Rearrangement is shared under a CC BY-NC 3.0 license and was authored, remixed, and/or curated by Chris Schaller via source content that was edited to the style and standards of the LibreTexts platform; a detailed edit history is available upon request.