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Characteristic Reactions of Nickel Ions (Ni²⁺)

  • Page ID
    97275
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    • Most common oxidation state: +2
    • M.P. 1453º
    • B.P. 2732º
    • Density 9.91 g/cm3
    • Characteristics: Nickel is a silvery-gray metal. Not oxidized by air under ordinary conditions. Easily dissolved in dilute nitric acid.

    Characteristic Reactions of Ni²⁺

    Nickel(II) ion forms a large variety of complex ions, such as the green hydrated ion, \(\ce{[Ni(H2O)6]^{2+}}\).

    Aqueous Ammonia

    Aqueous ammonia precipitates green gelatinous Ni(OH)2:

    \[\ce{Ni^{2+}(aq) + 2NH3(aq) + 2H2O(l) <=> Ni(OH)2(s) + 2NH4^{+}(aq)}\] Ni3a.gif

    The nickel(II) hydroxide precipitate dissolves in excess ammonia to form a blue complex ion:

    \[\ce{Ni(OH)2(s) + 6NH3(aq) <=> [Ni(NH3)6]^{2+}(aq) + 2OH^{-}(aq) }\] Ni3b.gif

    Sodium Hydroxide

    Sodium hydroxide also precipitates nickel(II) hydroxide:

    \[\ce{Ni^{2+}(aq) + 2OH^{-}(aq) <=> Ni(OH)2(s)}\] Ni3a.gif

    Nickel(II) hydroxide does not dissolve in excess \(\ce{NaOH}\).

    Dimethylglyoxime

    Addition of an alcoholic solution of dimethylglyoxime to an ammoniacal solution of Ni(II) gives a rose-red precipitate, abbreviated \(\ce{Ni(dmg)2}\):

    \[\ce{[Ni(NH3)6]^{2+}(aq) + 2(CH3CNOH)2(alc) <=> Ni[ONC(CH3)C(CH3)NOH]2(s) + 2NH4^{+}(aq) + 4NH3(aq)}\] Ni5a.gif

    Sulfide

    Black \(\ce{NiS}\) is precipitated by basic solutions containing sulfide ion:

    \[\ce{Ni^{2+}(aq) + S2^{-}(aq) <=> NiS(s)}\] Ni5b.gif

    Nickel(II) sulfide is not precipitated by adding \(\ce{H2S}\) in an acidic solution. In spite of this, \(\ce{NiS}\) is only slightly soluble in \(\ce{HCl}\) and has to be dissolved in hot nitric acid or aqua regia, because \(\ce{NiS}\) changes to a different crystalline form with different properties.

    No Reaction

    \(\ce{Cl^{-}}\), \(\ce{SO4^{2-}}\)


    Characteristic Reactions of Nickel Ions (Ni²⁺) is shared under a not declared license and was authored, remixed, and/or curated by James P. Birk.