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Characteristic Reactions of Copper Ions (Cu²⁺)

  • Page ID
    97269
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    • Most common oxidation states: +1, +2
    • M.P. 1083º
    • B.P. 2582º
    • Density 8.92 g/cm3
    • Characteristics: Copper is a reddish-yellow, rather inactive metal. Dissolves readily in \(\ce{HNO3}\) and in hot, concentrated \(\ce{H2SO4}\).

    Characteristic reactions of Cu²⁺

    The +2 oxidation state is more common than the +1. Copper(II) is commonly found as the blue hydrated ion, \(\ce{[Cu(H2O)4]^{2+}}\).

    Aqueous Ammonia

    Copper(II) ion reacts with stoichiometric quantities of aqueous ammonia to precipitate light blue Cu(OH)2. Some basic salts may also form.

    \[\ce{Cu2+(aq) + 2NH3(aq) + 3H2O(l) <=> Cu(OH)2(s) + 2NH4+(aq)}\]

    Cu3appt.gif

    The precipitate dissolves in excess ammonia to form a dark blue complex ion:

    \[\ce{Cu(OH)2(s) + 4NH3(aq) <=> [Cu(NH3)4]2+(aq) + 2OH-(aq) }\]

    Cu3bppt.gif

    Sodium Hydroxide

    Sodium hydroxide precipitates copper(II) hydroxide:

    \[\ce{Cu2+(aq) + 2OH-(aq) <=> Cu(OH)2(s)}\]

    Cu3appt.gif

    The precipitate does not dissolve in excess sodium hydroxide unless the NaOH solution is very concentrated. However, the precipitate will dissolve upon addition of concentrated ammonia solution.

    Potassium Ferrocyanide

    Potassium ferrocyanide precipitates red-brown copper(II) ferrocyanide from Cu2+ solutions:

    \[\ce{2Cu2+(aq) + [Fe(CN)6]4-(aq) <=> Cu2[Fe(CN)6](s)}\]

    Cu5ppt.gif

    This test is very sensitive. The precipitate is soluble in aqueous ammonia.

    Note: Many metal ions form ferrocyanide precipitates, so potassium ferrocyanide is not a good reagent for separating metal ions. It is used more commonly as a confirmatory test.

    No Reaction

    \(\ce{Cl^{-}}\), \(\ce{SO4^{2-}}\)


    This page titled Characteristic Reactions of Copper Ions (Cu²⁺) is shared under a not declared license and was authored, remixed, and/or curated by James P. Birk.

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