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Chemistry LibreTexts

Rate Laws

When studying a chemical reaction, it is important to consider not only the chemical properties of the reactants, but also the conditions under which the reaction occurs, the mechanism by which it takes place, the rate at which it occurs, and the equilibrium toward which it proceeds. According to the law of mass action, the rate of a chemical reaction at a constant temperature depends only on the concentrations of the substances that influence the rate. The substances that influence the rate of reaction are usually one or more of the reactants, but can occasionally be a product. Another influence on the rate of reaction can be a catalyst that does not appear in the balanced overall chemical equation. The rate law can only be experimentally determined and can be used to predict the relationship between the rate of a reaction and the concentrations of reactants.