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Chemistry LibreTexts

Atomic Scattering Factor

A measure of the scattering power of an isolated atom (also known as the atomic form factor). The scattering factor depends on the scattering amplitude of an individual atom and also the Bragg angle of scattering. It depends on the type of radiation  involved .

X-ray scattering

The scattering from a crystal of an X-ray beam results from the interaction between the electric component of the incident electromagnetic radiation and the electrons in the crystal. Tightly bound electrons scatter coherently (Rayleigh scattering); free electrons scatter incoherently (Compton scattering). The scattering process from atomic electrons in a crystal lattice has both coherent and incoherent components, and is described as Thomson scattering.

The scattering amplitude from a neutral atom depends on the number of electrons (\Z\) = the atomic number) and also on the Bragg angle \(\theta\) – destructive interference among waves scattered from the individual electrons reduces the intensity at other than zero scattering angle. For \(\theta=0\) the scattering amplitude is normally equal to \(Z\). However, the scattering factor is modified by anomalous scattering if the incident wavelength is near an absorption edge of the scattering element.

The X-ray scattering factor is evaluated as the Fourier transform of the electron density distribution of an atom or ion, which is calculated from theoretical wavefunctions for free atoms.

See also

  1. Electron diffraction. C. Colliex, J. M. Cowley, S. L. Dudarev, M. Fink, J. Gjønnes, R. Hilderbrandt, A. Howie, D. F. Lynch, L. M. Peng, G. Ren, A. W. Ross, V. H. Smith Jr, J. C. H. Spence, J. W. Steeds, J. Wang, M. J. Whelan and B. B. Zvyagin. International Tables for Crystallography(2006). Vol. C, ch. 4.3, pp. 259-429
  2. Intensity of  diffracted  intensities. P. J. Brown, A. G. Fox, E. N. Maslen, M. A. O'Keefe and B. T. M. Willis. International Tables for Crystallography (2006). Vol. C, ch. 6.1, pp. 554-595
  3. Neutron techniques. I. S. Anderson, P. J. Brown, J. M. Carpenter, G. Lander, R. Pynn, J. M. Rowe, O. Schärpf, V. F. Sears and B. T. M. Willis. International Tables for Crystallography (2006). Vol. C, ch. 4.4, pp. 430-487